Electron transfer rate modulation in a compact Re(I) donor-acceptor complex.
Yue Y, Grusenmeyer T, Ma Z, Zhang P, Schmehl RH, Beratan DN, Rubtsov IV.
Yue Y, et al.
Dalton Trans. 2015 May 14;44(18):8609-16. doi: 10.1039/c4dt02145b.
Dalton Trans. 2015.
PMID: 25600849
Formation of the charge transfer state with the rate constant of (10 ps)(-1) has recently been reported for the complex fac-[Re(I)(CO)3(DCEB)(3DMABN)] (ReEBA); where 3DMABN is 3-dimethylaminobenzonitrile, serving as an electron donor, and DCEB is 4,4'-(dicarboxyethyl)-2,2-bipyrid …
Formation of the charge transfer state with the rate constant of (10 ps)(-1) has recently been reported for the complex fac-[Re(I)(CO)3(DCEB …