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Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A.
Wang C, Yu M, Kyle AF, Jakubec P, Dixon DJ, Schrock RR, Hoveyda AH. Wang C, et al. Among authors: schrock rr. Chemistry. 2013 Feb 18;19(8):2726-40. doi: 10.1002/chem.201204045. Epub 2013 Jan 23. Chemistry. 2013. PMID: 23345004 Free PMC article.
Kinetically E-selective macrocyclic ring-closing metathesis.
Shen X, Nguyen TT, Koh MJ, Xu D, Speed AW, Schrock RR, Hoveyda AH. Shen X, et al. Among authors: schrock rr. Nature. 2017 Jan 19;541(7637):380-385. doi: 10.1038/nature20800. Epub 2017 Jan 9. Nature. 2017. PMID: 28068669 Free PMC article.
161 results