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Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond.
Liu F, Velkos G, Krylov DS, Spree L, Zalibera M, Ray R, Samoylova NA, Chen CH, Rosenkranz M, Schiemenz S, Ziegs F, Nenkov K, Kostanyan A, Greber T, Wolter AUB, Richter M, Büchner B, Avdoshenko SM, Popov AA. Liu F, et al. Among authors: rosenkranz m. Nat Commun. 2019 Feb 4;10(1):571. doi: 10.1038/s41467-019-08513-6. Nat Commun. 2019. PMID: 30718550 Free PMC article.
Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.
Junghans K, Schlesier C, Kostanyan A, Samoylova NA, Deng Q, Rosenkranz M, Schiemenz S, Westerström R, Greber T, Büchner B, Popov AA. Junghans K, et al. Among authors: rosenkranz m. Angew Chem Int Ed Engl. 2015 Nov 2;54(45):13411-5. doi: 10.1002/anie.201505870. Epub 2015 Sep 9. Angew Chem Int Ed Engl. 2015. PMID: 26350440 Free PMC article.
Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.
Junghans K, Ghiassi KB, Samoylova NA, Deng Q, Rosenkranz M, Olmstead MM, Balch AL, Popov AA. Junghans K, et al. Among authors: rosenkranz m. Chemistry. 2016 Sep 5;22(37):13098-107. doi: 10.1002/chem.201601655. Epub 2016 Jul 26. Chemistry. 2016. PMID: 27459520 Free PMC article.
Confining the spin between two metal atoms within the carbon cage: redox-active metal-metal bonds in dimetallofullerenes and their stable cation radicals.
Samoylova NA, Avdoshenko SM, Krylov DS, Thompson HR, Kirkhorn AC, Rosenkranz M, Schiemenz S, Ziegs F, Wolter AUB, Yang S, Stevenson S, Popov AA. Samoylova NA, et al. Among authors: rosenkranz m. Nanoscale. 2017 Jun 14;9(23):7977-7990. doi: 10.1039/c7nr02288c. Nanoscale. 2017. PMID: 28574078 Free PMC article.
Quinoidal Azaacenes: 99 % Diradical Character.
Intorp SN, Hodecker M, Müller M, Tverskoy O, Rosenkranz M, Dmitrieva E, Popov AA, Rominger F, Freudenberg J, Dreuw A, Bunz UHF. Intorp SN, et al. Among authors: rosenkranz m. Angew Chem Int Ed Engl. 2020 Jul 20;59(30):12396-12401. doi: 10.1002/anie.201915977. Epub 2020 Apr 28. Angew Chem Int Ed Engl. 2020. PMID: 32190951 Free PMC article.
305 results