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Practical synthesis and evaluation of the biological activities of 1alpha,25-dihydroxyvitamin D3 antagonists, 1alpha,25-dihydroxyvitamin D3-26,23-lactams. Designed on the basis of the helix 12-folding inhibition hypothesis.
Nakano Y, Kato Y, Imai K, Ochiai E, Namekawa J, Ishizuka S, Takenouchi K, Tanatani A, Hashimoto Y, Nagasawa K. Nakano Y, et al. Among authors: nagasawa k. J Med Chem. 2006 Apr 20;49(8):2398-406. doi: 10.1021/jm050738x. J Med Chem. 2006. PMID: 16610783
1alpha,25-Dihydroxyvitamin D(3)-26,23-lactam analogues function as vitamin D receptor antagonists in human and rodent cells.
Ishizuka S, Kurihara N, Hiruma Y, Miura D, Namekawa J, Tamura A, Kato-Nakamura Y, Nakano Y, Takenouchi K, Hashimoto Y, Nagasawa K, Roodman GD. Ishizuka S, et al. Among authors: nagasawa k. J Steroid Biochem Mol Biol. 2008 Jun;110(3-5):269-77. doi: 10.1016/j.jsbmb.2007.11.007. Epub 2008 Apr 22. J Steroid Biochem Mol Biol. 2008. PMID: 18501591 Free PMC article.
Tanatani, H. Kobayashi, R. Shimazawa, H. Koshino, Y. Hashimoto, K. Nagasawa, Synthesis of 1alpha,25-dihydroxy vitamin D(3)-26,23-lactams (DLAMs), a novel series of 1alpha,25-dihydroxy vitamin D(3) antagonist, Bioorg. ...
Tanatani, H. Kobayashi, R. Shimazawa, H. Koshino, Y. Hashimoto, K. Nagasawa, Synthesis of 1alpha,25-dihydroxy vitamin D(3)-26, …
Origin of stereocontrol in guanidine-bisurea bifunctional organocatalyst that promotes α-hydroxylation of tetralone-derived β-ketoesters: asymmetric synthesis of β- and γ-substituted tetralone derivatives via organocatalytic oxidative kinetic resolution.
Odagi M, Furukori K, Yamamoto Y, Sato M, Iida K, Yamanaka M, Nagasawa K. Odagi M, et al. Among authors: nagasawa k. J Am Chem Soc. 2015 Feb 11;137(5):1909-15. doi: 10.1021/ja511149y. Epub 2015 Jan 29. J Am Chem Soc. 2015. PMID: 25580909
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