Pancake-bonding of semiquinone radicals under variable temperature and pressure conditions.
Bogdanov NE, Milašinović V, Zakharov BA, Boldyreva EV, Molčanov K.
Bogdanov NE, et al. Among authors: molcanov k.
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2020 Apr 1;76(Pt 2):285-291. doi: 10.1107/S2052520620002772. Epub 2020 Mar 24.
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2020.
PMID: 32831231
The effects of temperature (100-370 K) and pressure (0-6 GPa) on the non-localized two-electron multicentric covalent bonds (`pancake bonding') in closely bound radical dimers were studied using single-crystal X-ray diffraction on a 4-cyano-N-methylpyridinium salt of 5,6-d …
The effects of temperature (100-370 K) and pressure (0-6 GPa) on the non-localized two-electron multicentric covalent bonds (`pancake …