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Determining relative f and d orbital contributions to M-Cl covalency in MCl6(2-) (M = Ti, Zr, Hf, U) and UOCl5(-) using Cl K-edge X-ray absorption spectroscopy and time-dependent density functional theory.
Minasian SG, Keith JM, Batista ER, Boland KS, Clark DL, Conradson SD, Kozimor SA, Martin RL, Schwarz DE, Shuh DK, Wagner GL, Wilkerson MP, Wolfsberg LE, Yang P. Minasian SG, et al. J Am Chem Soc. 2012 Mar 28;134(12):5586-97. doi: 10.1021/ja2105015. Epub 2012 Mar 9. J Am Chem Soc. 2012. PMID: 22404133
Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy.
La Pierre HS, Minasian SG, Abubekerov M, Kozimor SA, Shuh DK, Tyliszczak T, Arnold J, Bergman RG, Toste FD. La Pierre HS, et al. Among authors: minasian sg. Inorg Chem. 2013 Oct 7;52(19):11650-60. doi: 10.1021/ic4020543. Epub 2013 Sep 11. Inorg Chem. 2013. PMID: 24024833
54 results