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2-Oxo-3-alkynoic acids, universal mechanism-based inactivators of thiamin diphosphate-dependent decarboxylases: synthesis and evidence for potent inactivation of the pyruvate dehydrogenase multienzyme complex.
Brown A, Nemeria N, Yi J, Zhang D, Jordan WB, Machado RS, Guest JR, Jordan F. Brown A, et al. Among authors: jordan wb, jordan f. Biochemistry. 1997 Jul 1;36(26):8071-81. doi: 10.1021/bi970094y. Biochemistry. 1997. PMID: 9201955
A new class of compounds, the 2-oxo-3-alkynoic acids with a phenyl substituent at carbon 4 was reported by the authors as potent irreversible and mechanism-based inhibitors of the thiamin diphosphate- (ThDP-) dependent enzyme pyruvate decarboxylase [Chiu, C.-F., & J …
A new class of compounds, the 2-oxo-3-alkynoic acids with a phenyl substituent at carbon 4 was reported by the authors as potent irreversibl …
NMR analysis of covalent intermediates in thiamin diphosphate enzymes.
Tittmann K, Golbik R, Uhlemann K, Khailova L, Schneider G, Patel M, Jordan F, Chipman DM, Duggleby RG, Hübner G. Tittmann K, et al. Among authors: jordan f. Biochemistry. 2003 Jul 8;42(26):7885-91. doi: 10.1021/bi034465o. Biochemistry. 2003. PMID: 12834340
Electronic and nuclear magnetic resonance spectroscopic features of the 1',4'-iminopyrimidine tautomeric form of thiamin diphosphate, a novel intermediate on enzymes requiring this coenzyme.
Baykal AT, Kakalis L, Jordan F. Baykal AT, et al. Among authors: jordan f. Biochemistry. 2006 Jun 20;45(24):7522-8. doi: 10.1021/bi060395k. Biochemistry. 2006. PMID: 16768448 Free PMC article.
Appropriate compounds were synthesized to create models for the 1',4'-imino tautomer of the 4'-aminopyrimidine ring of thiamin diphosphate recently found to exist on the pathway of enzymatic reactions requiring this cofactor [Jordan, F., and Nemeria, N. S. (2005) Bi …
Appropriate compounds were synthesized to create models for the 1',4'-imino tautomer of the 4'-aminopyrimidine ring of thiamin diphosphate r …
Elucidation of the chemistry of enzyme-bound thiamin diphosphate prior to substrate binding: defining internal equilibria among tautomeric and ionization states.
Nemeria N, Korotchkina L, McLeish MJ, Kenyon GL, Patel MS, Jordan F. Nemeria N, et al. Among authors: jordan f. Biochemistry. 2007 Sep 18;46(37):10739-44. doi: 10.1021/bi700838q. Epub 2007 Aug 23. Biochemistry. 2007. PMID: 17715948
., Chakraborty, S., Baykal, A., Korotchkina, L., Patel, M. S., and Jordan, F. (2007) Proc. Natl. Acad. Sci. U.S.A. 104, 78-82.]. The ability to detect both the aminopyrimidine and iminopyrimidine tautomeric forms of thiamin diphosphate on enzymes has enabled us to a …
., Chakraborty, S., Baykal, A., Korotchkina, L., Patel, M. S., and Jordan, F. (2007) Proc. Natl. Acad. Sci. U.S.A. 104, 78-82. …
564 results