We have developed a palladium-catalyzed addition of a C-Si bond of acylsilanes across a range of unactivated allenes. The reaction proceeds with complete regioselectivity, in which a silyl group binds to the central carbon of the allene, allowing for the straightforward access to functionalized alkenylsilane derivatives.
Keywords: C−Si Bond Activation; Insertion; Organosilicon Compounds; Pd Catalysis; Silylation.
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