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Diverse Approaches for Enantioselective C-H Functionalization Reactions Using Group 9 Cp(x) M(III) Catalysts.
Yoshino T, Satake S, Matsunaga S. Yoshino T, et al. Chemistry. 2020 Jun 10;26(33):7346-7357. doi: 10.1002/chem.201905417. Epub 2020 Apr 9. Chemistry. 2020. PMID: 31994236 Review.
Transition-metal-catalyzed C-H functionalization reactions with Cp*M(III) catalysts (M=Co, Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic difficulties in achieving catalytic stereocontrol using these catalysts due to the …
Transition-metal-catalyzed C-H functionalization reactions with Cp*M(III) catalysts (M=Co, Rh, Ir) have found a wide variety of appli …
Iridium(III) Catalysts with an Amide-Pendant Cyclopentadienyl Ligand: Double Aromatic Homologation Reactions of Benzamides by Fourfold C-H Activation.
Tomita E, Yamada K, Shibata Y, Tanaka K, Kojima M, Yoshino T, Matsunaga S. Tomita E, et al. Angew Chem Int Ed Engl. 2020 Jun 22;59(26):10474-10478. doi: 10.1002/anie.202003009. Epub 2020 Apr 28. Angew Chem Int Ed Engl. 2020. PMID: 32232939 Free article.
The synthesis, characterization, and catalytic performance of iridium(III) catalysts that bear an amide-pendant cyclopentadienyl ligand ([Cp(A) IrI(2) ](2) ) is reported. These [Cp(A) IrI(2) ](2) catalysts were obtained from the complexation of a Cp(A) ligand precur …
The synthesis, characterization, and catalytic performance of iridium(III) catalysts that bear an amide-pendant cyclopentadienyl liga …
Synthesis of 1,1'-Spirobiindane-7,7'-Disulfonic Acid and Disulfonimide: Application for Catalytic Asymmetric Aminalization.
Kurihara T, Satake S, Hatano M, Ishihara K, Yoshino T, Matsunaga S. Kurihara T, et al. Chem Asian J. 2018 Sep 4;13(17):2378-2381. doi: 10.1002/asia.201800341. Epub 2018 May 9. Chem Asian J. 2018. PMID: 29644792 Free article.
1,1'-Spirobiindane-7,7'-disulfonic acid (SPISA) and 1,1'-spirobiindane-7,7'-disulfonimide were synthesized from 1,1'-spirobiindane-7,7'-diol (SPINOL) in 4 steps using a Pd-catalyzed Newman-Kwart rearrangement as a key step. These new catalysts possessing a rigid spirocycli …
1,1'-Spirobiindane-7,7'-disulfonic acid (SPISA) and 1,1'-spirobiindane-7,7'-disulfonimide were synthesized from 1,1'-spirobiindane-7,7'-diol …