The influence of structure and composition on precipitation phenomena in Al-bearing BCC/HCP Mg alloys are studied via diffusion couple technique. Interdiffusion induced by the resultant composition gradient results in a change in crystal structure from HCP to BCC in the diffusion zone. The Vickers hardness in the diffusion zone is much higher than that in the Mg-5.5at.%Al and Mg-38at.%Li, which is attributed to the chemical ordering by nano-sized secondary ordered D03-Mg3Al precipitation in the BCC Mg-Li-Al diffusion zone. The reasons for different precipitation in Al-bearing Mg alloys with various matrices are discussed. Generating ordered precipitates can be an effective approach to improve both strength and ductility in HCP Mg alloys.
Keywords: Mg alloy; diffusion couple; ordered phases; phase transformation; precipitation strengthening.