Enantioselective Nickel-Catalyzed Hydrosilylation of 1,1-Disubstituted Allenes.
Liu T, Mao XR, Song S, Chen ZY, Wu Y, Xu LP, Wang P.
Liu T, et al.
Angew Chem Int Ed Engl. 2023 Mar 6;62(11):e202216878. doi: 10.1002/anie.202216878. Epub 2023 Feb 7.
Angew Chem Int Ed Engl. 2023.
PMID: 36651564
Here, we report the first example of Ni-catalyzed asymmetric hydrosilylation of 1,1-disubstituted allenes with high level of regioselectivities and enantioselectivities. The key to achieve this stereoselective hydrosilylation reaction was the development of the SPSiOL-deri …
Here, we report the first example of Ni-catalyzed asymmetric hydrosilylation of 1,1-disubstituted allenes with high level of regioselectivit …