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Page 1
Excitonic Effects in Polymeric Photocatalysts.
Wang H, Jin S, Zhang X, Xie Y. Wang H, et al. Angew Chem Int Ed Engl. 2020 Dec 14;59(51):22828-22839. doi: 10.1002/anie.202002241. Epub 2020 Aug 31. Angew Chem Int Ed Engl. 2020. PMID: 32609426 Review.
Selective CO2 Photoreduction to CH4 via Pdδ+ -Assisted Hydrodeoxygenation over CeO2 Nanosheets.
Wang Z, Zhu J, Zu X, Wu Y, Shang S, Ling P, Qiao P, Liu C, Hu J, Pan Y, Zhu J, Sun Y, Xie Y. Wang Z, et al. Angew Chem Int Ed Engl. 2022 Jul 25;61(30):e202203249. doi: 10.1002/anie.202203249. Epub 2022 Jun 2. Angew Chem Int Ed Engl. 2022. PMID: 35591804
Furthermore, theoretical calculations suggest the Pd doping could regulate the formation energy barrier of the key intermediates CO* and CH(3) O*, thus making CO(2) reduction to CH(4) become the favorable process. ...
Furthermore, theoretical calculations suggest the Pd doping could regulate the formation energy barrier of the key intermediates CO* …
Ultrathin In-Plane Heterostructures for Efficient CO2 Chemical Fixation.
Jin S, Shao W, Chen S, Li L, Shang S, Zhao Y, Zhang X, Xie Y. Jin S, et al. Angew Chem Int Ed Engl. 2022 Jan 17;61(3):e202113411. doi: 10.1002/anie.202113411. Epub 2021 Nov 30. Angew Chem Int Ed Engl. 2022. PMID: 34783135
As revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and quasi in situ X-ray photoelectron spectroscopy (XPS), Lewis acid-base sites could readily activate CO(2) to (.) CO(2) (-) species, which is the key intermediate radical for CO(2 …
As revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and quasi in situ X-ray photoelectron spectrosco …
Selective CO2 Photoreduction Enabled by Water-stable Cu-based Metal-organic Framework Nanoribbons.
Zhao Y, Chen R, Luo J, Zhu J, Wu Y, Qiao P, Yan W, Pan Y, Zhu J, Zu X, Sun Y. Zhao Y, et al. Chemphyschem. 2024 Mar 1;25(5):e202300368. doi: 10.1002/cphc.202300368. Epub 2024 Jan 26. Chemphyschem. 2024. PMID: 38193665
In situ Fourier-transform infrared spectra and Gibbs free energy calculations unravel the formation of the key intermediate COOH* and CO* is an exothermic and spontaneous process, whereas the competitive hydrogen evolution reaction is endothermic and non-spontaneous, which …
In situ Fourier-transform infrared spectra and Gibbs free energy calculations unravel the formation of the key intermediate COOH* and …
Atom-Economical Synthesis of Dimethyl Carbonate from CO2 : Engineering Reactive Frustrated Lewis Pairs on Ceria with Vacancy Clusters.
Li L, Liu W, Chen R, Shang S, Zhang X, Wang H, Zhang H, Ye B, Xie Y. Li L, et al. Angew Chem Int Ed Engl. 2022 Dec 19;61(51):e202214490. doi: 10.1002/anie.202214490. Epub 2022 Nov 22. Angew Chem Int Ed Engl. 2022. PMID: 36307955
By taking CeO(2) as a model system, we illustrate that FLP sites can efficiently accelerate the coupling and conversion of key intermediates. As demonstrated, CeO(2) with rich FLP sites shows improved reaction activity and achieves a high yield of DMC up to 15.3 mmol g(-1) …
By taking CeO(2) as a model system, we illustrate that FLP sites can efficiently accelerate the coupling and conversion of key interm …