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Page 1
Kernel Homology in Gold Nanoclusters.
Zhuang S, Liao L, Yuan J, Wang C, Zhao Y, Xia N, Gan Z, Gu W, Li J, Deng H, Yang J, Wu Z. Zhuang S, et al. Angew Chem Int Ed Engl. 2018 Nov 19;57(47):15450-15454. doi: 10.1002/anie.201808997. Epub 2018 Oct 25. Angew Chem Int Ed Engl. 2018. PMID: 30290044
Tertiary Chiral Nanostructures from C-H⋅⋅⋅F Directed Assembly of Chiroptical Superatoms.
Shen H, Xu Z, Wang L, Han YZ, Liu X, Malola S, Teo BK, Häkkinen H, Zheng N. Shen H, et al. Angew Chem Int Ed Engl. 2021 Oct 4;60(41):22411-22416. doi: 10.1002/anie.202108141. Epub 2021 Sep 1. Angew Chem Int Ed Engl. 2021. PMID: 34347339
We report the synthesis and structure of tertiary chiral nanostructures with 100 % optical purity. A novel synthetic strategy, using chiral reducing agent, R and S-BINAPCuBH(4) (BINAP is 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl), is developed to access to atomically pre …
We report the synthesis and structure of tertiary chiral nanostructures with 100 % optical purity. A novel synthetic strategy, using chiral …
Organocatalytic Asymmetric Synthesis of an Advanced Intermediate of (+)-Sarain A.
Hu XN, Wu DP, Xu YP, Huang PQ. Hu XN, et al. Chemistry. 2021 Jan 7;27(2):609-613. doi: 10.1002/chem.202004261. Epub 2020 Dec 1. Chemistry. 2021. PMID: 33044771
This approach featured the employment of an organocatalytic asymmetric Michael addition reaction and a nitrogen-to-carbon chirality transfer to forge three chiral centers, as well as a catalytic hydrosilylation for the chemoselective reduction of a key lactam intermediate. …
This approach featured the employment of an organocatalytic asymmetric Michael addition reaction and a nitrogen-to-carbon chirality transfer …
Alkynyl-Protected Chiral Bimetallic Ag22 Cu7 Superatom with Multiple Chirality Origins.
Deng G, Lee K, Deng H, Malola S, Bootharaju MS, Häkkinen H, Zheng N, Hyeon T. Deng G, et al. Angew Chem Int Ed Engl. 2023 Mar 13;62(12):e202217483. doi: 10.1002/anie.202217483. Epub 2023 Jan 18. Angew Chem Int Ed Engl. 2023. PMID: 36581588
Structural analysis reveals that Ag(22) Cu(7) exhibits multiple chirality origins, including the metal core, the metal-ligand interface and the ligand layer. Furthermore, the circular dichroism spectra of R/S-Ag(22) Cu(7) are obtained by employing appropriate chiral molecu …
Structural analysis reveals that Ag(22) Cu(7) exhibits multiple chirality origins, including the metal core, the metal-ligand interface and …
14 results