Umpolung of hemiaminals: titanocene-catalyzed dehydroxylative radical coupling reactions with activated alkenes

Angew Chem Int Ed Engl. 2013 Mar 18;52(12):3494-8. doi: 10.1002/anie.201210088. Epub 2013 Feb 18.

Authors

Xiao Zheng¹, Xi-Jie Dai, Hong-Qiu Yuan, Chen-Xi Ye, Jie Ma, Pei-Qiang Huang

Affiliation

¹ Department of Chemistry and Fujian Provincial Key Laboratory of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, P.R. China. zxiao@xmu.edu.cn

PMID: 23420540
DOI: 10.1002/anie.201210088

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkenes / chemistry*
Catalysis
Coordination Complexes / chemistry
Heterocyclic Compounds, 3-Ring / chemical synthesis
Heterocyclic Compounds, 3-Ring / chemistry
Hydroxyl Radical / chemistry*
Organometallic Compounds / chemistry*
Stereoisomerism
Titanium / chemistry

Substances

Alkenes
Coordination Complexes
Heterocyclic Compounds, 3-Ring
Organometallic Compounds
stemoamide
titanocene
Hydroxyl Radical
Titanium