Crude Oil Drop Penetration into Permeates Using a Slotted Pore Membrane

ACS Omega. 2021 Oct 12;6(42):27763-27772. doi: 10.1021/acsomega.1c03227. eCollection 2021 Oct 26.

Abstract

The primary focus of the presented research is to come up with a model that could be utilized to evaluate the permeate content (concentration) of oil drops using a straight (nonconverging) slotted microstructured membrane. The content (concentration) of crude drops in the permeate with a nonconverging slit structure membrane has not been studied before, and the study presented would be a good contribution to the literature. A comparison between the use of a converging (narrowing toward the inside) and a nonconverging slotted pore microstructured membrane is made for the purpose of removing oil content from the produced water. Due to the drag force, the droplets pass through the membrane slots; however, the static force acts in the opposite direction and tries to reject droplets by the membrane. At a certain point, these two forces balance the effect of each other, which is known as "100% cutoff through the membrane". A linear line is obtained by joining the 100% cutoff or rejection point to the 0% rejection point, which is referred to as the "linear fit" in this paper. The linear fit approach could be utilized for estimating rejection below the 100% cutoff point. Various types of crude oil drops obtained from different locations were analyzed experimentally, and the results were compared with the presented model. The proposed model was found to be in agreement with the different types of oil drops. Experimental and predicted results showed that the nonconverging slotted microstructured membrane provided low friction to oil drops through the membrane as compared to the converging slots. Furthermore, the developed model can be utilized to predict the overall oil content in the permeate. This research has great importance and will allow researchers around the globe to estimate crude oil concentration within the allowable limits.