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Trans-pyridine tetraammine complexes of RuII and RuIII with N7-coordinated purine nucleosides.
Zhao M, Clarke MJ. Zhao M, et al. J Biol Inorg Chem. 1999 Jun;4(3):318-24. doi: 10.1007/s007750050318. J Biol Inorg Chem. 1999. PMID: 10439077
As expected, the Pyr ligand slows DNA binding by trans-[(H2O)(Pyr)(NH3)4RuII]2+ relative to [(H2O)(NH3)5RuII]2+ and favors reduction of RuIII by about 150 mV. The pyridine ligand also promotes the disproportionation of RuIII to afford the corresponding complexes of …
As expected, the Pyr ligand slows DNA binding by trans-[(H2O)(Pyr)(NH3)4RuII]2+ relative to [(H2O)(NH3)5RuII]2+ and favors reduction of R …
Effects of trans-pyridine ligands on the interactions of RuII and RuIII ammine complexes N7-coordinated to purine nucleosides and DNA.
Zhao M, Clarke MJ. Zhao M, et al. J Biol Inorg Chem. 1999 Jun;4(3):325-40. doi: 10.1007/s007750050319. J Biol Inorg Chem. 1999. PMID: 10439078
Disproportionation of [py(NH3)4RuIII]n,-DNA occurs according to the rate law: d[RuII-GDNA]/dt = k0[RuIII-GDNA] + k1[RuIII-GDNA][OH-], where k0 = 5.4 x 10(-4) s-1 and k1 = 8.8 M-1 s-1 at 25 degrees C, mu = 0.1. The appearance of [(Gua)(py)(NH3)4RuIII] under argon, wh …
Disproportionation of [py(NH3)4RuIII]n,-DNA occurs according to the rate law: d[RuII-GDNA]/dt = k0[RuIII-GDNA] + k1[RuIII-GDNA …
Ultrafine PtRu Dilute Alloy Nanodendrites for Enhanced Electrocatalytic Methanol Oxidation.
Zhang S, Rong H, Yang T, Bai B, Zhang J. Zhang S, et al. Chemistry. 2020 Mar 26;26(18):4025-4031. doi: 10.1002/chem.201904229. Epub 2019 Oct 30. Chemistry. 2020. PMID: 31596524
For the methanol oxidation reaction, PtRu NDs showed the highest forward peak current density (2.66 mA cm(-2) , 1.14 A/mg(Pt) ) and the best stability compared to those of pure-Pt nanodendrites (pure-Pt NDs), commercial PtRu/C and commercial Pt/C catalysts....
For the methanol oxidation reaction, PtRu NDs showed the highest forward peak current density (2.66 mA cm(-2) , 1.14 A/mg(Pt) ) and t …
Stabilization of a molecular water oxidation catalyst on a dye-sensitized photoanode by a pyridyl anchor.
Zhu Y, Wang D, Huang Q, Du J, Sun L, Li F, Meyer TJ. Zhu Y, et al. Nat Commun. 2020 Sep 14;11(1):4610. doi: 10.1038/s41467-020-18417-5. Nat Commun. 2020. PMID: 32929088 Free PMC article.
By contrast, immobilization of the Ru-bda catalyst on TiO(2) with the 4,4'-dipyridyl anchoring ligand can maintain the monomeric structure of catalyst and gives relatively stable photoanodes with photocurrents that reach to 1.7 mA cm(-2) with an optimized, applied bias pho …
By contrast, immobilization of the Ru-bda catalyst on TiO(2) with the 4,4'-dipyridyl anchoring ligand can maintain the monomeric structure o …
Ordered Macroporous Superstructure of Nitrogen-Doped Nanoporous Carbon Implanted with Ultrafine Ru Nanoclusters for Efficient pH-Universal Hydrogen Evolution Reaction.
Wu YL, Li X, Wei YS, Fu Z, Wei W, Wu XT, Zhu QL, Xu Q. Wu YL, et al. Adv Mater. 2021 Mar;33(12):e2006965. doi: 10.1002/adma.202006965. Epub 2021 Feb 18. Adv Mater. 2021. PMID: 33598974
Benefiting from the highly interconnected reticular macro-nanospaces, this superstrucure affords unparalleled performance for pH-universal HER, with order of magnitude higher mass activity compared to the benchmark Pt/C. Notably, an exceptionally low overpotential of only 13 mV@1 …
Benefiting from the highly interconnected reticular macro-nanospaces, this superstrucure affords unparalleled performance for pH-universal H …
Synthesis of two novel macroporous silica-based impregnated polymeric composites and their application in highly active liquid waste partitioning by extraction chromatography.
Zhang A, Kuraoka E, Hoshi H, Kumagai M. Zhang A, et al. J Chromatogr A. 2004 Dec 24;1061(2):175-82. doi: 10.1016/j.chroma.2004.11.023. J Chromatogr A. 2004. PMID: 15641360
MA(III) was believed to flow into MA-mRE group along with Gd(III) due to their similar adsorption properties towards CMPO/SiO2-P. Based on positions of MA(III) appeared in light and heavy RE(III), an improved MAREC process for MA(III) partitioning from …
MA(III) was believed to flow into MA-mRE group along with Gd(III) due to their similar adsorption properties towards CMPO/SiO2 …
Ruthenium(III) maltolato-nitroimidazole complexes: synthesis and biological activity.
Kennedy DC, Wu A, Patrick BO, James BR. Kennedy DC, et al. J Inorg Biochem. 2006 Dec;100(12):1974-82. doi: 10.1016/j.jinorgbio.2006.07.001. Epub 2006 Jul 25. J Inorg Biochem. 2006. PMID: 16938347
The Ru(III) metronidazole-maltolato and -ethylmaltolato complexes, trans-[RuL(2)(metro)(2)]CF(3)SO(3) (L=ma (1a) or etma (1b)), have been synthesized and tested for potential anti-tumour activity against the human breast cancer cell line MDA-MB-435S using a so-called MTT a …
The Ru(III) metronidazole-maltolato and -ethylmaltolato complexes, trans-[RuL(2)(metro)(2)]CF(3)SO(3) (L=ma (1a) or etma (1b)), have …
Tris(pyronato)- and tris(pyridonato)-ruthenium(III) complexes and solution NMR studies.
Kennedy DC, Wu A, Patrick BO, James BR. Kennedy DC, et al. Inorg Chem. 2005 Sep 19;44(19):6529-35. doi: 10.1021/ic050034d. Inorg Chem. 2005. PMID: 16156610
The water-soluble Ru(III) maltolato, ethylmaltolato, and pyridonato complexes, Ru(O-O')3 (O-O' = ma (1a), etma (1b), pyd (2a)), were synthesized (Hma = 3-hydroxy-2-methyl-4-pyrone, Hetma = 2-ethyl-3-hydroxy-4-pyrone, Hpyd = 3-hydroxy-1,2-dimethyl-4-pyridone). The complexes …
The water-soluble Ru(III) maltolato, ethylmaltolato, and pyridonato complexes, Ru(O-O')3 (O-O' = ma (1a), etma (1b), pyd (2a)), were …
13 results