Crystal structure of (E)-2-amino-4-methyl-sulfanyl-6-oxo-1-{[(thiophen-2-yl)-methyl-idene]-amino}-1,6-di-hydro-pyrimidine-5-carbo-nitrile

Acta Crystallogr E Crystallogr Commun. 2015 Oct 14;71(Pt 11):1319-21. doi: 10.1107/S205698901501885X. eCollection 2015 Nov 1.

Abstract

The title compound, C11H9N5OS2, a 1-thio-phen-2-yl-methyl-ene-amino-pyrimidine derivative, displays an essentially planar C-NH2 group. The conformation across the N=C bond linking the pyrimidine and thienyl groups is E. The pyrimidine and thienyl ring systems subtend an inter-planar angle of 42.72 (5)°. In the crystal, mol-ecules are linked by N-H⋯Nnitrile and N-H⋯O=C hydrogen bonds, forming chains parallel to the b axis.

Keywords: N—H⋯N and N—H⋯O hydrogen bonds.; crystal structure; pyrimidine; thien­yl.