The origin of magnetism in transition metal-doped ZrO2 thin films: experiment and theory

J Phys Condens Matter. 2013 Oct 30;25(43):436003. doi: 10.1088/0953-8984/25/43/436003. Epub 2013 Oct 4.

Abstract

We have investigated the magnetic properties of Fe/Co/Ni-doped ZrO2 laser ablated thin films in comparison with the known results of Mn-doped ZrO2, which is thought to be a promising material for spintronics applications. It is found that doping with a transition metal can induce room temperature ferromagnetism in 'fake' diamond. Theoretical analysis based on density functional theory confirms the experimental measurements, by revealing that the magnetic moments of Mn- and Ni-doped ZrO2 thin films are much larger than that of Fe- or Co-doped ZrO2 thin films. Most importantly, our calculations confirm that Mn- and Ni-doped ZrO2 show a ferromagnetic ground state in comparison to Co- and Fe-doped ZrO2, which favor an antiferromagnetic ground state.

Publication types

  • Research Support, Non-U.S. Gov't