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Indium-Mediated Stereoselective Allylation.
Kumar D, Vemula SR, Balasubramanian N, Cook GR. Kumar D, et al. Acc Chem Res. 2016;49(10):2169-2178. doi: 10.1021/acs.accounts.6b00362. Epub 2016 Oct 4. Acc Chem Res. 2016. PMID: 27700084
In this Account, we describe indium-mediated synthetic methods for the preparation of chiral amines with the aim to present a balance of practical method development, novel asymmetric chemistry, and mechanistic understanding that impact multiple chemical and materials scie …
In this Account, we describe indium-mediated synthetic methods for the preparation of chiral amines with the aim to present a balance …
Ambidexterity and Left-Handedness Induced by Geminally Disubstituted gamma Amino Acid Residues in Chiral 3(10) Helices.
Debnath S, Rajalakshmi VS, Kumar D, Das B, Vasudev PG, Satpati P, Chatterjee S. Debnath S, et al. Among authors: kumar d. ACS Omega. 2023 Sep 21;8(39):36370-36385. doi: 10.1021/acsomega.3c05124. eCollection 2023 Oct 3. ACS Omega. 2023. PMID: 37810672 Free PMC article.
Chirality is an omnipresent feature in nature's architecture starting from simple molecules like amino acids to complex higher-order structures viz. proteins, DNA, and RNA. ...Here, we report, for the first time, the ambidextrous and left-handed helical conformations in th …
Chirality is an omnipresent feature in nature's architecture starting from simple molecules like amino acids to complex higher-order …
Effect of temperature on elastic properties of CNT-polyethylene nanocomposite and its interface using MD simulations.
Singh A, Kumar D. Singh A, et al. Among authors: kumar d. J Mol Model. 2018 Jun 27;24(7):178. doi: 10.1007/s00894-018-3716-6. J Mol Model. 2018. PMID: 29951941
Based on the results, it is concluded that, irrespective of temperature condition, a nanocomposite reinforced with CNT of larger chirality (i.e., armchair) yields a higher value of Young's modulus of the nanocomposite and its interface. ...
Based on the results, it is concluded that, irrespective of temperature condition, a nanocomposite reinforced with CNT of larger chiralit …
Revisiting the problem of crystallisation and melting of selenium.
Kumar D, Gohil S, Gokhale M, Chalke B, Ghosh S. Kumar D, et al. J Phys Condens Matter. 2021 Jun 7;33(29). doi: 10.1088/1361-648X/ac0025. J Phys Condens Matter. 2021. PMID: 33975297
These strands are held together by weak forces and can easily be separated. These chains occasionally get entangled to form chiral structures and often meander about destroying long range orientation and translation order in a continuous manner. ...
These strands are held together by weak forces and can easily be separated. These chains occasionally get entangled to form chiral st …