Construction of Hollow Co₃O₄@ZnIn₂S₄ p-n Heterojunctions for Highly Efficient Photocatalytic Hydrogen Production

Photocatalysts derived from semiconductor heterojunctions for water splitting have bright prospects in solar energy conversion. Here, a Co₃O₄@ZIS p-n heterojunction was successfully created by developing two-dimensional ZnIn₂S₄ on ZIF-67-derived hollow Co₃O₄ nanocages, realizing efficient spatial separation of the electron-hole pair. Moreover, the black hollow structure of Co₃O₄ considerably increases the range of light absorption and the light utilization efficiency of the heterojunction avoids the agglomeration of ZnIn₂S₄ nanosheets and further improves the hydrogen generation rate of the material. The obtained Co₃O₄(20) @ZIS showed excellent photocatalytic H₂ activity of 5.38 mmol g^-1·h^-1 under simulated solar light, which was seven times more than that of pure ZnIn₂S₄. Therefore, these kinds of constructions of hollow p-n heterojunctions have a positive prospect in solar energy conversion fields.