Pore Structure and Gas Content Characteristics of Lower Jurassic Continental Shale Reservoirs in Northeast Sichuan, China

Nanomaterials (Basel). 2023 Feb 20;13(4):779. doi: 10.3390/nano13040779.

Abstract

The Jurassic shale in the northeastern Sichuan Basin is one of the main target intervals for continental shale gas exploitation. Research on the pore structure and gas-bearing properties of shales is the key issue in target interval optimization. Through core observation, geochemistry, bulk minerals, scanning electron microscopy, nitrogen adsorption, and isothermal adsorption experiments, various lithofacies with different pore structure characteristics were clarified. In addition, the factors that control gas-bearing properties were discussed, and a continental shale gas enrichment model was finally established. The results show that the Jurassic continental shale in the northeastern Sichuan Basin can be classified into six lithofacies. Organic pores, intergranular pores, interlayer pores in clay minerals, intercrystalline pores in pyrite framboids, and dissolution pores can be observed in shale samples. Pore structures varied in different shale lithofacies. The contact angle of shales is commonly less than 45°, leading to complex wettability of pores in the shales. Free gas content is mainly controlled by the organic matter (OM) content and the brittleness in the Jurassic shale. The adsorbed gas content is mainly controlled by the OM content, clay mineral type, and water saturation of the shales. The enrichment mode of the Lower Jurassic continental shale gas in the northeastern Sichuan Basin is established. Paleoenvironments control the formation of organic-rich shales in the center part of lakes. The "baffle" layer helps the confinement and high pressure, and the complex syncline controls the preservation, forming the enrichment pattern of the complex syncline-central baffle layer.

Keywords: Northeastern Sichuan Basin; continental shale gas; gas-bearing property; pore structure.

Grants and funding

The authors would like to acknowledge the support of the State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum (no. PRP/open-2201); the National Major Science and Technology Projects of China (2016ZX05034001-005 & 2017ZX05035-02); the National Key Research and Development Program of China (the DREAM—Deep Resource Exploration and Advanced Mining; No. 2018YFC0603701); the China Geological Survey (Nos. DD20160083 and DD20190011); and the Cooperative Project of the Chinese Academy of Geological Sciences with the SinoPec Shengli Oilfield Company (No. P22065).