Properties in Langmuir Monolayers and Langmuir-Blodgett Films of a Block Copolymer Based on N-Isopropylacrylamide and 2,2,3,3-Tetrafluropropyl Methacrylate

Olga Zamyshlyayeva; Zarina Shaliagina; Maria Simonova; Alexander Filippov; Maxim Baten'kin

doi:10.3390/polym14235193

Properties in Langmuir Monolayers and Langmuir-Blodgett Films of a Block Copolymer Based on N-Isopropylacrylamide and 2,2,3,3-Tetrafluropropyl Methacrylate

Polymers (Basel). 2022 Nov 29;14(23):5193. doi: 10.3390/polym14235193.

Authors

Olga Zamyshlyayeva¹, Zarina Shaliagina¹, Maria Simonova², Alexander Filippov², Maxim Baten'kin³

Affiliations

¹ Department of High Molecular Compounds and Colloidal Chemistry, Faculty of Chemistry, Lobachevsky State University, Gagarina pr. 23, Nizhny Novgorod 603950, Russia.
² Institute of Macromolecular Compounds Russian Academy of Science, Bolshoy pr. 31, Saint-Petersburg 199004, Russia.
³ G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinin Street, Nizhny Novgorod 603950, Russia.

Abstract

The amphiphilic block copolymer poly(N-isopropylacrylamide)-Ge(C₆F₅)₂-poly(2,2,3,3-tetrafluoropropyl methacrylate) was prepared by the reaction of chain transfer to bis-(pentafluorophenyl)germane during the polymerization of N-isopropylacrylamide and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The conversion of the block copolymer was 68% and the molecular weight of the sample was 490,000 g/mol. The colloidal chemical properties of Langmuir monolayers and Langmuir-Blodgett films of synthesized block copolymer have been studied. For comparison, a functional polymer, namely, poly-N-isopropylacrylamide with terminal -Ge(C₆F₅)₂H group, was synthesized and studied. The concentrations of spreading solutions were selected and the effect of subphase acidity on the formation of monolayers of macromolecules of the block copolymer was studied. It was found that regardless of the acidity of the subphase, high pressure of fracture of films are characteristic of monolayers of collapse pressures π_max = (48-61) mN/m. The morphology of the Langmuir-Blodgett films of functional polymer exhibit isolated elongated micelles with high densities in the form of "octopus" on the periphery of which there are terminal hydrophobic groups. For the Langmuir-Blodgett film of block copolymer, a comb-like structure is observed with characteristic protrusions.

Keywords: Langmuir monolayer; Langmuir-Blodgett films; block copolymer; poly-N-isopropylacrylamide; synthesis.

Grants and funding

The study of the synthesis of polymers was performed within the framework of the state assignment in the sphere of scientific activity (topic 122012100166-4).