Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin

We report aircraft observations of extreme levels of HCl and the dihalogens Cl₂, Br₂, and BrCl in an industrial plume near the Great Salt Lake, Utah. Complete depletion of O₃ was observed concurrently with halogen enhancements as a direct result of photochemically produced halogen radicals. Observed fluxes for Cl₂, HCl, and NO_x agreed with facility-reported emissions inventories. Bromine emissions are not required to be reported in the inventory, but are estimated as 173 Mg year^-1 Br₂ and 949 Mg year^-1 BrCl, representing a major uncounted oxidant source. A zero-dimensional photochemical box model reproduced the observed O₃ depletions and demonstrated that bromine radical cycling was principally responsible for the rapid O₃ depletion. Inclusion of observed halogen emissions in both the box model and a 3D chemical model showed significant increases in oxidants and particulate matter (PM_2.5) in the populated regions of the Great Salt Lake Basin, where winter PM_2.5 is among the most severe air quality issues in the U.S. The model shows regional PM_2.5 increases of 10%-25% attributable to this single industrial halogen source, demonstrating the impact of underreported industrial bromine emissions on oxidation sources and air quality within a major urban area of the western U.S.