Radiocarbon in the atmospheric gases and PM₁₀ aerosol around the Paks Nuclear Power Plant, Hungary

Our study shows a one-year-long, monthly integrated continuous monitoring campaign of gaseous radiocarbon emission and ambient air compared with 4 event-like, weekly (168 h) atmospheric aerosol radiocarbon data in every season of 2019, at 4 locations (n = 16 aerosol sample) around the Paks Nuclear Power Plant, Hungary. The study shows the first aerosol radiocarbon results around a nuclear power plant measured by accelerator mass spectrometry in Hungary. There was no dominant contribution detected in the atmospheric CO₂ gas fraction, but we could detect excess radiocarbon in the total gaseous carbon fraction at almost every sampling point around the Paks Nuclear Power Plant. The highest Δ¹⁴C value in the total gaseous carbon form was 157.9 ± 4.6‰ in November and the highest Δ ¹⁴C value in the CO₂ fraction was 86.1 ± 4.0‰ in December during 2019. Observed ¹⁴C activity excess is not higher than previously published values around the Paks Nuclear Power plant at the same sampling points (Molnár et al., 2007; Varga et al., 2020). Our aerosol radiocarbon measurements show that there is no significant contribution from the nuclear power plant to the atmospheric PM₁₀ fraction. We could not detect a Δ ¹⁴C value higher than 0‰ in any season. The results show that the simple aerosol sampling, without pre-treatment of the filters, is appropriate for the measurement of excess radiocarbon at the vicinity of nuclear power plants. The applied preparation and measurement method can be applicable for detection of hot (¹⁴C) particles and early identification of radiocarbon emission from nuclear power plants in the PM₁₀ fraction.