Detailed characterization of bio-oil from pyrolysis of non-edible seed-cakes by Fourier Transform Infrared Spectroscopy (FTIR) and gas chromatography mass spectrometry (GC-MS) techniques

J Chromatogr B Analyt Technol Biomed Life Sci. 2017 Jul 15:1058:47-56. doi: 10.1016/j.jchromb.2017.05.014. Epub 2017 May 12.

Abstract

Bio-oil obtained from pyrolysis is highly complicated mixture with valued chemicals. In order to reduce the complexity for unambiguous characterization of components present in bio-oil, solvent extractions using different solvents with increasing polarity have been adopted. The fractions have been analyzed by Fourier transform infrared (FTIR) spectroscopy for identifying the functional groups and Gas chromatography-mass spectrometry (GC-MS), for detailed characterization of components present in various fractions, thereby providing in-depth information at molecular level of various components in bio-oil. This paper reveals the potential of the analytical techniques in identification and brings out the similarities as well as differences in the components present in the bio-oil obtained from two non-edible oil seed-cakes, viz., Jatropha and Karanjia.

Keywords: Bio-oil; FTIR; Gas chromatography mass spectrometry; Jatropha seed-cake; Karanjia seed-cake; Pyrolysis.

MeSH terms

  • Biofuels / analysis*
  • Biomass
  • Gas Chromatography-Mass Spectrometry / methods*
  • Hot Temperature
  • Jatropha / chemistry*
  • Pongamia / chemistry*
  • Seeds / chemistry
  • Spectroscopy, Fourier Transform Infrared / methods*

Substances

  • Biofuels