Improved pyrolysis behavior of ammonium polyphosphate-melamine-expandable (APP-MEL-EG) intumescent fire retardant coating system using ceria and dolomite as additives for I-beam steel application

Joshua B Zoleta; Gevelyn B Itao; Vannie Joy T Resabal; Arnold A Lubguban; Ryan D Corpuz; Mayumi Ito; Naoki Hiroyoshi; Carlito Baltazar Tabelin

doi:10.1016/j.heliyon.2019.e03119

Improved pyrolysis behavior of ammonium polyphosphate-melamine-expandable (APP-MEL-EG) intumescent fire retardant coating system using ceria and dolomite as additives for I-beam steel application

Heliyon. 2019 Dec 30;6(1):e03119. doi: 10.1016/j.heliyon.2019.e03119. eCollection 2020 Jan.

Authors

Joshua B Zoleta^{1

2}, Gevelyn B Itao¹, Vannie Joy T Resabal¹, Arnold A Lubguban¹, Ryan D Corpuz¹, Mayumi Ito³, Naoki Hiroyoshi³, Carlito Baltazar Tabelin²

Affiliations

¹ Department of Materials and Resources Engineering and Technology, College of Engineering and Technology, Mindanao State University-Iligan Institute of Technology, Iligan City, 9200, Philippines.
² School of Minerals and Energy Resources Engineering, The University of New South Wales, Sydney, NSW, 2052, Australia.
³ Laboratory of Mineral Processing and Resources Recycling, Division of Sustainable Resources Engineering, Hokkaido University, Sapporo, 060-8628, Japan.

Abstract

This study describes the effects of ceria (CeO₂) and dolomite [CaMg(CO₃)₂] additives on the pyrolysis behavior and fire resistive property of conventional intumescent flame retardant (IFR) coating system for I-beam steel substrate called ammonium polyphosphate-melamine-expandable graphite (APP-MEL-EG) system. The fire resistance of various formulations was evaluated using the standard vertical Bunsen burner fire test. Thermogravimetric analysis (TGA) was used to understand the degradation of coating formulations. Observations by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) demonstrated that significant amounts of additives favored the formation of homogeneous compacted char structures, which were predominantly composed of carbon (C), phosphorus (P) and oxygen (O). These three main components of the char were also found to be in various binding combinations with other lighter elements like nitrogen (N) and hydrogen (H) as illustrated by the attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy results. X-ray photoelectron spectroscopy (XPS) further suggest that polyethylene([(CH₂-C₂H₂-CH₂)^n-]) free radicals were abundant on the char surface for the two best formulations and the binding energy of this radical promoted the formation of aromatic carbon chains that enhanced the char's thermal stability. This means that the selection of appropriate additives and combinations of flame-retardant ingredients could significantly change the morphology of the char layer and improve its thermal stability during fire exposure.

Keywords: Ammonium polyphosphate; Ceria; Char formation; Chemical engineering; Dolomite; Fire retardant; I-beam; Intumescent coating; Materials chemistry; Materials science; Pyrolysis; Thermal stability; XPS.