Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers

Polymers (Basel). 2022 Jan 27;14(3):524. doi: 10.3390/polym14030524.

Abstract

The effect of polyester oligoethylene adipate molecular weight, diisocyanate structure, and chain extender on the properties of epoxyurethane-based oligomer elastomers was studied in this research. Oligoethylene adipates were obtained via polycondensation of adipic acid and ethylene glycol. Epoxyurethane oligomers were synthesized according to a two-step route with an oligodiisocyanate as an intermediate product. The elastomers with hard urethane hydroxyl blocks were synthesized from oligodiisocyanates. The deformation and strength properties of the elastomers were studied.

Keywords: DSC; FTIR; NMR; contact angle of water; epoxy terminal oligomers; hard and soft segments; mechanical properties; structure; urethane elastomers.