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Comprehensive analysis of the effective and intra-particle diffusion of weakly retained compounds in silica hydrophilic interaction liquid chromatography columns.
Redón L, Subirats X, Chapel S, Januarius T, Broeckhoven K, Rosés M, Cabooter D, Desmet G. Redón L, et al. J Chromatogr A. 2024 Jan 4;1713:464529. doi: 10.1016/j.chroma.2023.464529. Epub 2023 Nov 23. J Chromatogr A. 2024. PMID: 38029660
For the weakly retained compounds (k' < 0.5) the D(part)/D(m)-values were found to be relatively high (order of 0.35-0.5), which directly reflects the high gamma(s)D(s)/D(m)-values that were observed (order 0.35-7)....

For the weakly retained compounds (k' < 0.5) the D(part)/D(m)-values were found to be relatively high (order of 0.35-0.5), which directly