Integration of capacitive deionization and forward osmosis for high water recovery and ultrapure water production: concept, modelling and performance analysis

Forward Osmosis (FO), a membrane desalination technology and Capacitive Deionization (CDI), an electrically operated desalination technology, are numerically integrated utilizing four different configurations for the high-water recovery rate and ultrapure water production from brackish water resource. To minimize the wastewater rejection, the CDI desorption stream is continuously fed to the FO unit, efficiently recovering the remaining freshwater. To produce ultrapure water, freshwater stream obtained from FO is provided to the CDI cell, which adsorbs the remaining dissolved solute particles. These two configurations serve the purpose of both industrial as well as domestic water supply requirements. Continuing this concept, the formation of the other two configurations allows us to obtain fresh water and ultrapure water simultaneously and up to a 90% freshwater recovery rate for the areas with inadequate supply. The performance parameters to assess the integration are the Water Recovery Rate (WRR) and Specific Energy Consumption (SEC). The first configuration (CDI-FO), proposed for a high freshwater recovery rate, resulted in 79.33% WRR with an SEC of 0.689$\mathrm{kWh}/m^3$. While, for the second configuration (FO-CDI), 34.25% water was recovered as 2.87 ppm ultrapure water along with 34.25% freshwater. The third proposed configuration (CDI-FO-CDI) had a WRR of 79.33%, 14.67% of which was recovered as ultrapure water of concentration 2.86 ppm. The fourth configuration (CDI-FO-FO) developed for high water recovery, removed the maximum of water from the feed stream with a WRR of 91.33% and remained energy-efficient, consuming an SEC of 0.908$\mathrm{kWh}/m^3$.