Inhibitory action of halogen-free fire retardants on combustion and volatile emission of bituminous components

The objective of this study is to quantitatively evaluate inhibitory action of halogen-free fire retardants (HFR) on combustion properties and volatile emission of such bituminous components as saturates, aromatics, resins, and asphaltenes (SARA). Thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR) tests were performed on SARA fractions containing matched fire retardants, respectively, and thermal kinetics parameters based on TG curves and functional and structural indices from FTIR spectra were calculated, respectively. The selected fire retardants have not affected the combustion process of SARA fractions, but the combustion temperature intervals are elevated and combustion progresses are retarded. Also, the char yields of SARA fractions are obviously increased by the matched fire retardants, improving their heat stability. The activation energy is elevated because of the added fire retardants, indicating combustion resistance of SARA fractions become larger. Additionally, the matched fire retardants inhibit the toxic gas emission in the combustion process of SARA fractions, but have few effects on gaseous product constituents. H₂O and CO₂ are identified as two typical released gases in various combustion phases of each SARA fraction. Finally, the added hydroxide play a role of fire retardants through cooling, dilution, adsorption, and neutralization, and the generated active oxide facilitates the expandable graphite (EG) and matrix to form densified and thick carbon layer. These suppress the volatile emission, and hinder the heat conduction and oxygen supply. Fire retardant composite exhibits the synergistic effect of fire retardancy and smoke inhibition in the combustion process of SARA fractions.