Boronic acid-linked fluorescent and colorimetric probes for copper ions

Chem Commun (Camb). 2008 Dec 7:(45):5915-7. doi: 10.1039/b814167c. Epub 2008 Oct 14.

Abstract

The first examples of boronic acid-linked fluorescent and colorimetric chemosensors for copper ions are reported; the monoboronic acid-conjugated rhodamine probe displays a highly selective fluorescent enhancement with Cu2+ among the various metal ions whereas the fluorescence of the bisboronic acid-conjugated fluorescein probe is selectively quenched by Cu2+, probably by way of a PET mechanism.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Boronic Acids / chemical synthesis
  • Boronic Acids / chemistry*
  • Cells, Cultured
  • Copper / chemistry*
  • Fluoresceins / chemical synthesis
  • Fluoresceins / chemistry*
  • Fluorescent Dyes / chemistry*
  • Rhodamines / chemical synthesis
  • Rhodamines / chemistry*
  • Spectrometry, Fluorescence
  • Zebrafish / physiology

Substances

  • Boronic Acids
  • Fluoresceins
  • Fluorescent Dyes
  • Rhodamines
  • Copper