Orientation Control of Hemispherical Janus Particles and Metal Coating on the Selective Surface To Excite Surface Plasmon Polaritons in the Micro-Kretschmann Geometry

Langmuir. 2017 Dec 26;33(51):14684-14690. doi: 10.1021/acs.langmuir.7b03572. Epub 2017 Dec 14.

Abstract

Asymmetric-shaped particles (the Janus particle) are difficult to be arranged in a uniform orientation on a solid substrate. This difficulty prevents further modification of the selective surface of the particles for fabrication of the Janus particles with anisotropy of the shape and surface. We successfully arranged hemispherical particles in a uniform orientation at the air-water interface. The particles were arranged on the solid substrate in a uniform orientation by transferring the particle film onto the substrate. This arrangement enabled the fabrication of the Janus particles with anisotropy of the shape and surface by selective deposition of a film on either the equatorial plane or the spherical surface. Additionally, we demonstrated the function of the microscopic Kretschmann geometry for excitation of the surface plasmon polaritons of a thin metal film on the equatorial plane of a single hemispherical particle.