Pd-catalyzed carbonyl insertion coupling reactions of a hypervalent iodoheterocycle with alcohols and amines

Shengj-Jun Luo; Yong-Xiang Ma; Yong-Min Liang

doi:10.3390/10010238

Pd-catalyzed carbonyl insertion coupling reactions of a hypervalent iodoheterocycle with alcohols and amines

Molecules. 2005 Jan 31;10(1):238-43. doi: 10.3390/10010238.

Authors

Shengj-Jun Luo¹, Yong-Xiang Ma, Yong-Min Liang

Affiliation

¹ State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.

Abstract

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

Publication types

Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Alcohols / chemical synthesis*
Alcohols / chemistry
Amines / chemical synthesis*
Amines / chemistry
Carbon / chemistry*
Catalysis / drug effects
Heterocyclic Compounds / chemical synthesis*
Heterocyclic Compounds / chemistry
Iodine Compounds / chemical synthesis*
Iodine Compounds / chemistry
Models, Biological
Palladium / pharmacology*

Substances

Alcohols
Amines
Heterocyclic Compounds
Iodine Compounds
Palladium
Carbon