MOF-Derived Cu@N-C Catalyst for 1,3-Dipolar Cycloaddition Reaction

Zhuangzhuang Wang; Xuehao Zhou; Shaofeng Gong; Jianwei Xie

doi:10.3390/nano12071070

MOF-Derived Cu@N-C Catalyst for 1,3-Dipolar Cycloaddition Reaction

Nanomaterials (Basel). 2022 Mar 24;12(7):1070. doi: 10.3390/nano12071070.

Authors

Zhuangzhuang Wang^{1

2}, Xuehao Zhou², Shaofeng Gong¹, Jianwei Xie^{1

2}

Affiliations

¹ College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou 425199, China.
² Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China.

Abstract

Cu(im)₂-derived Cu@N-C composites were used for the first time as efficient heterogeneous catalysts for one-pot 1,3-dipolar cycloaddition of terminal alkynes, aryl halides, and sodium azide to preparation of 1,4-disubstituted 1,2,3-triazoles with broad substrate scope and high yields. The catalyst can be easily reused without the changes of structure and morphology, and the heterogeneity nature was confirmed from the catalyst recyclability and metal leaching test.

Keywords: 1,2,3-triazole; MOF-derived materials; click chemistry; heterogeneous copper catalysts.

Abstract

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