Abstract
Schiff base tetraazamacrocyclic ligand, L (C(40)H(28)N(4)) and its complexes of types, [MLX(2)] and [CuL]X(2) (M=Co(II), Ni(II), Zn(II); X=Cl(-), NO(3)(-)) were synthesized and characterized by elemental analyses, mass, (1)H NMR, IR, UV-vis, magnetic susceptibility and molar conductance data. An octahedral geometry has been proposed for all the complexes except the copper(II) complexes which have a square planar environment. The reducing power of the Co(II) and Cu(II) complexes have been checked and compared. The ligand (L) and its complexes have also been screened against different fungi and bacteria in vitro.
Publication types
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Comparative Study
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Research Support, Non-U.S. Gov't
MeSH terms
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Anti-Bacterial Agents / chemical synthesis
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Anti-Bacterial Agents / chemistry*
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Anti-Bacterial Agents / pharmacology
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Antifungal Agents / chemical synthesis
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Antifungal Agents / chemistry*
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Antifungal Agents / pharmacology
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Bacteria / drug effects
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Cobalt
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Copper
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Drug Evaluation, Preclinical
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Fungi / drug effects
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Ligands
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Microbial Sensitivity Tests
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Molecular Structure
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Nickel
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Nuclear Magnetic Resonance, Biomolecular
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Organometallic Compounds / pharmacology
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Oxidation-Reduction
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Reducing Agents / chemical synthesis
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Reducing Agents / chemistry*
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Reducing Agents / pharmacology
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Schiff Bases / chemical synthesis
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Schiff Bases / chemistry
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Schiff Bases / pharmacology
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Spectrophotometry, Infrared
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Spectrophotometry, Ultraviolet
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Zinc
Substances
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Anti-Bacterial Agents
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Antifungal Agents
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Ligands
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Organometallic Compounds
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Reducing Agents
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Schiff Bases
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Cobalt
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Copper
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Nickel
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Zinc