Experimental and computational studies of Criegee intermediate reactions with NH3 and CH3NH2.
Chhantyal-Pun R , Shannon RJ , Tew DP , Caravan RL , Duchi M , Wong C , Ingham A , Feldman C , McGillen MR , Khan MAH , Antonov IO , Rotavera B , Ramasesha K , Osborn DL , Taatjes CA , Percival CJ , Shallcross DE , Orr-Ewing AJ .
Chhantyal-Pun R , et al.
Phys Chem Chem Phys. 2019 Jul 3;21(26):14042-14052. doi: 10.1039/c8cp06810k.
Phys Chem Chem Phys. 2019.
PMID: 30652179
Temperature-dependent rate coefficients, k(CH2OO + NH3) = (3.1 0.5) 10-20T2 exp(1011 48/T) cm3 s-1 and k(CH2OO + CH3NH2) = (5 2) 10-19T2 exp(1384 96/T) cm3 s-1 were obtained in the 240 to 320 K range. Both the reactions of CH2OO were found to be independent of press …
Temperature-dependent rate coefficients, k(CH2OO + NH3) = (3.1 0.5) 10-20T2 exp(1011 48/T) cm3 s-1 and k(CH2OO + CH3NH2) = (5 2) 10-1 …