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Mapping the transformation [{Ru(II)(CO)(3)Cl(2)}(2)]-->[Ru(I) (2)(CO)(4)](2+): implications in binuclear water-gas shift chemistry.
Majumdar M, Sinha A, Ghatak T, Patra SK, Sadhukhan N, Rahaman SM, Bera JK. Majumdar M, et al. Chemistry. 2010 Feb 22;16(8):2574-85. doi: 10.1002/chem.200902797. Chemistry. 2010. PMID: 20077542
The complete sequence of reactions in the base-promoted reduction of [{Ru(II)(CO)(3)Cl(2)}(2)] to [Ru(I) (2)(CO)(4)](2+) has been unraveled. ...Premature quenching of the reaction resulted in the isolation of a trinuclear Ru(I) (2)Ru(II) complex [{R
The complete sequence of reactions in the base-promoted reduction of [{Ru(II)(CO)(3)Cl(2)}(2)] to [Ru(I) (2)(CO)(4)](2+) has b …
Unexpected effect of catalyst concentration on photochemical CO(2) reduction by trans(Cl)-Ru(bpy)(CO)(2)Cl(2): new mechanistic insight into the CO/HCOO(-) selectivity.
Kuramochi Y, Itabashi J, Fukaya K, Enomoto A, Yoshida M, Ishida H. Kuramochi Y, et al. Chem Sci. 2015 May 1;6(5):3063-3074. doi: 10.1039/c5sc00199d. Epub 2015 Mar 12. Chem Sci. 2015. PMID: 28706681 Free PMC article.
The result has led us to propose a new mechanism in which HCOO(-) is selectively produced by the formation of a Ru(i)-Ru(i) dimer as the catalyst intermediate. This reaction mechanism predicts that the Ru-Ru bond dissociates in the reaction of the dime …
The result has led us to propose a new mechanism in which HCOO(-) is selectively produced by the formation of a Ru(i)-Ru(i) di …