Electrical Current Map and Bulk Conductivity of Carbon Fiber-Reinforced Nanocomposites

Polymers (Basel). 2019 Nov 12;11(11):1865. doi: 10.3390/polym11111865.

Abstract

A suitably modified resin film infusion (RFI) process was used for manufacturing carbon fiber-reinforced composites (CFRCs) impregnated with a resin containing nanocages of glycidyl polyhedral oligomeric silsesquioxane (GPOSS) for enhancing flame resistance and multi-wall carbon nanotubes (MWCNTs) to contrast the electrical insulating properties of the epoxy resin. The effects of the different numbers (7, 14 and 24) of the plies on the equivalent direct current (DC) and alternating current (AC) electrical conductivity were evaluated. All the manufactured panels manifest very high values in electrical conductivity. Besides, for the first time, CFRC strings were analyzed by tunneling atomic force microscopy (TUNA) technique. The electrical current maps highlight electrically conductive three-dimensional networks incorporated in the resin through the plies of the panels. The highest equivalent bulk conductivity is shown by the seven-ply panel characterized by the parallel (σ//0°) in-plane conductivity of 16.19 kS/m. Electrical tests also evidence that the presence of GPOSS preserves the AC electrical stability of the panels.

Keywords: carbon–carbon composites (CCCS); electrical properties; particle reinforcement; structural composites; thermosetting resins; tunneling atomic force microscopy (TUNA) technique.