Heteropolyacids as green and reusable catalysts for the synthesis of 3,1,5-benzoxadiazepines

Molecules. 2007 Feb 26;12(2):255-62. doi: 10.3390/12020255.

Abstract

Synthesis of 3,1,5-benzoxadiazepines from the condensation of o-phenylenediamine (o-PDA) and acyl chlorides in the presence of a catalytic amount of various heteropolyacids (HPAs) is reported.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acids*
  • Azepines / chemical synthesis*
  • Azepines / chemistry
  • Benzodiazepines / chemical synthesis*
  • Benzodiazepines / chemistry
  • Catalysis
  • Cyclization
  • Heterocyclic Compounds / chemistry*
  • Magnetic Resonance Spectroscopy
  • Mass Spectrometry
  • Molecular Structure
  • Structure-Activity Relationship

Substances

  • Acids
  • Azepines
  • Heterocyclic Compounds
  • Benzodiazepines