MnCo₂O₄/Ni₃S₄ nanocomposite for hybrid supercapacitor with superior energy density and long-term cycling stability

MnCo₂O₄ is regarded as a good electrode material for supercapacitor due to its high specific capacity and good structural stability. However, its poor electrical conductivity limits its wide-range applications. To solve this issue, we integrated the MnCo₂O₄ with Ni₃S₄, which has a good electrical conductivity, and synthesized a MnCo₂O₄/Ni₃S₄ nanocomposite using a two-step hydrothermal process. Comparing with individual MnCo₂O₄ and Ni₃S₄, the MnCo₂O₄/Ni₃S₄ nanocomposite showed a higher specific capacity and a better cycling stability as the electrode for the supercapacitor. The specific capacity value of the MnCo₂O₄/Ni₃S₄ electrode was 904.7 C g^-1 at 1 A g^-1 with a potential window of 0-0.55 V. A hybrid supercapacitor (HSC), assembled using MnCo₂O₄/Ni₃S₄ and active carbon as the cathode and anode, respectively, showed a capacitance of 116.4 F g^-1 at 1 A g^-1, and a high energy density of 50.7 Wh kg^-1 at 405.8 W kg^-1. Long-term electrochemical stability tests showed an obvious increase of the HSC's capacitance after 5500 charge/discharge cycles, reached a maximum value of ∼162.7% of its initial value after 25,000 cycles, and then remained a stable value up to 64,000 cycles. Simultaneously, its energy density was increased to 54.2 Wh kg^-1 at 380.3 W kg^-1 after 64,000 cycles.