Kinetic and Mechanistic Studies of the Formation of Silver Nanoparticles by Nicotinamide as a Reducing Agent

Here, in the present study, silver nanoparticles (SNPs) in the size range 6-10 nm have been synthesized by a chemical reduction method using nicotinamide (NTA), an anti-inflammatory agent, and cetyltrimethylammonium bromide (CTAB), a good stabilizing agent, to preparing the nanoparticles in the 6-10 nm size range. Kinetic studies on the formation of SNPs have been performed spectrophotometrically at 410 nm (strong plasmon band) in aqueous medium as a function of [AgNO₃], [NTA], [NaOH], and [CTAB]. The plot of ln(A _∞ - A _t ) versus time exhibited a straight line and the pseudo-first-order rate constants of different variables were calculated from its slope. On the basis of experimental findings, a plausible mechanism was proposed for the formation of SNPs colloid. From the mechanism, it is proved that the reduction of silver ions proceeded through the formation of silver oxide in colloidal form by their reaction with hydroxide ions and NTA after performing their function and readily undergo hydrolysis to form nicotinic acid as a hydrolysis product with the release of ammonia gas. The preliminary characterization of the SNPs was carried out by using a UV-visible spectrophotometer. The detailed characterization of SNPs was also carried out using other experimental techniques such as Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and powder X-ray diffraction (PXRD). SNPs show a remarkable catalytic activity of up to 90% for the reduction of the cationic dye methylene blue.