Hybrid Composites of Polylactide with Basalt and Carbon Fibers and Their Thermal Treatment

Materials (Basel). 2018 Dec 28;12(1):95. doi: 10.3390/ma12010095.

Abstract

In this research, polylactide was hybrid-reinforced and heat-treated in order to obtain durable structural materials with the use of eco-friendly components. Differential scanning calorimetry (DSC) analysis, tensile tests at various temperatures, Vicat tests, impact tests, and microscopic observations were conducted on the annealed and non-heat-treated specimens. The theoretical and true density, as well as water absorption, were also determined. The simultaneous introduction of chopped carbon and basalt fibers in equal mass fractions of 7.5% and 12.5% resulted in satisfactory increases in stiffness and tensile strength. The reinforcing effect was more efficient for the heat-treated composites, especially at elevated temperatures. Heat treatment significantly increased the degree of crystallinity of the matrix, improving heat resistance and reducing water absorption. It also reduced the stress concentrations in the injection-molded specimens.

Keywords: bio-based; biopolymer; cold crystallization; natural fiber; structural biocomposites.