Exploring Regioselective Bond Cleavage and Cross-Coupling Reactions using a Low-Valent Nickel Complex.
Desnoyer AN, Friese FW, Chiu W, Drover MW, Patrick BO, Love JA.
Desnoyer AN, et al.
Chemistry. 2016 Mar 14;22(12):4070-7. doi: 10.1002/chem.201504959. Epub 2016 Feb 16.
Chemistry. 2016.
PMID: 26879766
Herein, we report a systematic study of the reactivity of a series of esters and thioesters with [{(dtbpe)Ni}2(mu-eta(2):eta(2)-C6H6)] (dtbpe=1,2-bis(di-tert-butyl)phosphinoethane), which is a source of (dtbpe)nickel(0). Trifluoromethylthioesters were found to form eta(2)- …
Herein, we report a systematic study of the reactivity of a series of esters and thioesters with [{(dtbpe)Ni}2(mu-eta(2):eta(2)-C6H6)] (dtbp …