Mg doped Li2FeSiO4/C nanocomposites synthesized by the solvothermal method for lithium ion batteries

Ajay Kumar; O D Jayakumar; Jagannath; Parisa Bashiri; G A Nazri; Vaman M Naik; Ratna Naik

doi:10.1039/c7dt03177g

Mg doped Li₂FeSiO₄/C nanocomposites synthesized by the solvothermal method for lithium ion batteries

Dalton Trans. 2017 Oct 14;46(38):12908-12915. doi: 10.1039/c7dt03177g. Epub 2017 Sep 19.

Authors

Ajay Kumar¹, O D Jayakumar, Jagannath, Parisa Bashiri, G A Nazri, Vaman M Naik, Ratna Naik

Affiliation

¹ Department of Physics and Astronomy, Wayne State Physics, Detroit, USA. rnaik@wayne.edu.

PMID: 28926060
DOI: 10.1039/c7dt03177g

Abstract

A series of porous Li₂Fe_1-xMg_xSiO₄/C (x = 0, 0.01, 0.02, 0.04) nanocomposites (LFS/C, 1Mg-LFS/C, 2Mg-LFS and 4Mg-LFS/C) have been synthesized via a solvo-thermal method using the Pluronic P123 polymer as an in situ carbon source. Rietveld refinement of the X-ray diffraction data of Li₂Fe_1-xMg_xSiO₄/C composites confirms the formation of the monoclinic P2₁ structure of Li₂FeSiO₄. The addition of Mg facilitates the growth of impurity-free Li₂FeSiO₄ with increased crystallinity and particle size. Despite having the same percentage of carbon content (∼15 wt%) in all the samples, the 1Mg-LFS/C nanocomposite delivered the highest initial discharge capacity of 278 mA h g^-1 (∼84% of the theoretical capacity) at the C/30 rate and also exhibited the best rate capability and cycle stability (94% retention after 100 charge-discharge cycles at 1C). This is attributed to its large surface area with a narrow pore size distribution and a lower charge transfer resistance with enhanced Li-ion diffusion coefficient compared to other nanocomposites.