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Palladium-catalyzed Kumada coupling reaction of bromoporphyrins with silylmethyl Grignard reagents: preparation of silylmethyl-substituted porphyrins as a multipurpose synthon for fabrication of porphyrin systems.
J Org Chem. 2012 Dec 7;77(23):10488-97. doi: 10.1021/jo302122f. Epub 2012 Nov 27.
J Org Chem. 2012.
PMID: 23167823
Regioselective β-silylation of porphyrins via iridium-catalyzed C-H bond activation.
Sugita N, Hayashi S, Shibata M, Endo T, Noji M, Takatori K, Takanami T.
Sugita N, et al.
Org Biomol Chem. 2016 Nov 2;14(43):10189-10192. doi: 10.1039/c6ob02243j.
Org Biomol Chem. 2016.
PMID: 27766340
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