Incorporation of ultrathin porous metal-free graphite carbon nitride nanosheets in polyvinyl chloride for efficient photodegradation

Solid-phase photocatalytic degradation of waste plastics is one of the promising approaches to solve the "white pollution" problem. In this work, a low cost, metal-free, environmentally friendly organic photocatalyst, graphite carbon nitride (g-C₃N₄), was used for the first time to successfully enhance the photodegradation of polyvinyl chloride (PVC) under simulated sunlight from its visible light photocatalytic capability, while its organic nature and abundant surface functional groups were beneficial for its good dispersion in plastics. It was found that the ultrathin porous g-C₃N₄ nanosheet synthesized from urea (the UCN sample) had much stronger photodegradation effect in PVC/g-C₃N₄ composite films than its thick block counterpart synthesized with melamine (the MCN sample) due to its larger specific surface area, higher pore volume, and enhanced photogenerated charge carrier separation. With the incorporation of only 1 wt% UCN sample into PVC, its mechanical properties were largely enhanced with the tensile strength increase of ∼ 45% and the elongation at break increase of ∼ 72%, and its weight loss increased ∼ 58% after 120 h irradiation in the weather resistance test chamber. ^·O₂^- and h⁺ produced by the UCN sample were found as the main active species in the photocatalytic degradation of PVC to dechlorinate PVC and decompose its long-chain molecules into short-chain small molecules until its final degradation into CO₂ and H₂O under ideal conditions.