Ag₃PO₄-Deposited TiO₂@Ti₃C₂ Petals for Highly Efficient Photodecomposition of Various Organic Dyes under Solar Light

Two-dimensional Ti₃C₂ MXenes can be used to fabricate hierarchical TiO₂ nanostructures that are potential photocatalysts. In this study, the photodecomposition of organic dyes under solar light was investigated using flower-like TiO₂@Ti₃C₂, deposited using narrow bandgap Ag₃PO₄. The surface morphology, crystalline structure, surface states, and optical bandgap properties were determined using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), nitrogen adsorption analysis, and UV-Vis diffuse reflectance spectroscopy (UV-DRS). Overall, Ag₃PO₄-deposited TiO₂@Ti₃C₂, referred to as Ag₃PO₄/TiO₂@Ti₃C₂, demonstrated the best photocatalytic performance among the as-prepared samples, including TiO₂@Ti₃C₂, pristine Ag₃PO₄, and Ag₃PO₄/TiO₂ P25. Organic dyes, such as rhodamine B (RhB), methylene blue (MB), crystal violet (CV), and methylene orange (MO), were efficiently degraded by Ag₃PO₄/TiO₂@Ti₃C₂. The significant enhancement of photocatalysis by solar light irradiation was attributed to the efficient deposition of Ag₃PO₄ nanoparticles on flower-like TiO₂@Ti₃C₂ with the efficient separation of photogenerated e-/h+ pairs, high surface area, and extended visible-light absorption. Additionally, the small size of Ag₃PO₄ deposition (ca. 4-10 nm diameter) reduces the distance between the core and the surface of the composite, which inhibits the recombination of photogenerated charge carriers. Free radical trapping tests were performed, and a photocatalytic mechanism was proposed to explain the synergistic photocatalysis of Ag₃PO₄/TiO₂@Ti₃C₂ under solar light.