Preparation and characterization of acetylated corn starch-(PVOH)/clay nanocomposite films

Katerina Katerinopoulou; Aris Giannakas; Kalouda Grigoriadi; Nektaria M Barkoula; Athanasios Ladavos

doi:10.1016/j.carbpol.2013.11.030

Preparation and characterization of acetylated corn starch-(PVOH)/clay nanocomposite films

Carbohydr Polym. 2014 Feb 15:102:216-22. doi: 10.1016/j.carbpol.2013.11.030. Epub 2013 Dec 1.

Authors

Katerina Katerinopoulou¹, Aris Giannakas², Kalouda Grigoriadi³, Nektaria M Barkoula⁴, Athanasios Ladavos⁵

Affiliations

¹ Department of Business Administration of Food and Agricultural Enterprises, Laboratory of Food Technology, University of Patras, Agrinio 30100, Greece. Electronic address: akaterin@cc.uoi.gr.
² Department of Business Administration of Food and Agricultural Enterprises, Laboratory of Food Technology, University of Patras, Agrinio 30100, Greece. Electronic address: agiannak@cc.uoi.gr.
³ Department of Materials Science and Engineering, University of Ioannina, Ioannina 45110, Greece. Electronic address: kalouda.grigoriadi@gmail.com.
⁴ Department of Materials Science and Engineering, University of Ioannina, Ioannina 45110, Greece. Electronic address: nbarkoul@cc.uoi.gr.
⁵ Department of Business Administration of Food and Agricultural Enterprises, Laboratory of Food Technology, University of Patras, Agrinio 30100, Greece. Electronic address: alantavo@cc.uoi.gr.

PMID: 24507275
DOI: 10.1016/j.carbpol.2013.11.030

Abstract

Acetylated corn starch (ACS)-based clay (NaMMT) nanocomposite films, with or without addition of polyvinyl alcohol (PVOH), were prepared by casting with glycerol as a plasticizer. The obtained nanocomposite structure was ascertained by XRD study for all polymer-clay nanocomposites. XRD patterns are indicative of an intercalated nanocomposite structure. Mechanical and thermomechanical properties of polymer nanocomposites were studied. The addition of clay induces significant reinforcing effects in the thermoplastic ACS systems. Replacement of glycerol with PVOH in the ACS-NaMMT system results in superior mechanical strength, due to the creation of hydrogen bonds between the ACS and the PVOH chains. Enhancement in water barrier properties was observed for all nanocomposite films, which reaches up to 67% for acetylated starch-PVOH-clay nanocomposites in comparison to acetylated thermoplastic starch, as indicated by water vapor transmission measurements.

Keywords: Acetylated corn starch; Clay nanocomposites; PVOH; Properties.