Hybridization of Co₃S₄ and Graphitic Carbon Nitride Nanosheets for High-performance Nonenzymatic Sensing of H₂O₂

The development of efficient H₂O₂ sensors is crucial because of their multiple functions inside and outside the biological system and the adverse effects that a higher concentration can cause. This work reports a highly sensitive and selective non-enzymatic electrochemical H₂O₂ sensor achieved through the hybridization of Co₃S₄ and graphitic carbon nitride nanosheets (GCNNS). The Co₃S₄ is synthesized via a hydrothermal method, and the bulk g-C₃N₄ (b-GCN) is prepared by the thermal polycondensation of melamine. The as-prepared b-GCN is exfoliated into nanosheets using solvent exfoliation, and the composite with Co₃S₄ is formed during nanosheet formation. Compared to the performances of pure components, the hybrid structure demonstrates excellent electroreduction towards H₂O₂. We investigate the H₂O₂-sensing performance of the composite by cyclic voltammetry, differential pulse voltammetry, and amperometry. As an amperometric sensor, the Co₃S₄/GCNNS exhibits high sensitivity over a broad linear range from 10 nM to 1.5 mM H₂O₂ with a high detection limit of 70 nM and fast response of 3 s. The excellent electrocatalytic properties of the composite strengthen its potential application as a sensor to monitor H₂O₂ in real samples. The remarkable enhancement of the electrocatalytic activity of the composite for H₂O₂ reduction is attributed to the synergistic effect between Co₃S₄ and GCNNS.