A systematic approach for how to find an appropriate polymer binder for high-capacity LIB anodes is presented in this study. As an example, a newly-developed SAlg-g-PAAm binder, alginate functionalized with sulfo groups and subsequently grafted with polyacrylamide, is used for the Si/C electrode. Various characteristics of the binder polymer itself, two basic characteristics of the electrode with respect to the binder, and the effect of the binder on cell performance are subsequently investigated. In all respects, the SAlg-g-PAAm polymer is a very promising binder for high-capacity anodes. The sulfo groups in the binder improve the ionic conductivities in both the binder and the electrode, leading to reduced charge transfer resistance. In addition, the sulfonation of the alginate grafted with polyacrylamide significantly enhances the mechanical and adhesion properties of the binder and consequently decreases the volume change generated during cycles. These advantages of the SAlg-g-PAAm binder ultimately lead to a considerable enhancement in the electrochemical performance of the high-capacity Si/C electrodes.
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